Owen, that'll give all the Windows environment settings which ACad knows of.
For the others (acad specific) available through the Lisp getenv, you should also check acad's registry settings. Open RegEditWinKey+R
regedit<Enter>
Then browse to several of acad's registry paths. Note these examples are for ACA 2013, the version (R19.0), vertical (ACAD-B004:409) and profile (Profiles\AutoCAD) folders may differ depending on your acad and settings:HKEY_CURRENT_USER\Software\Autodesk\AutoCAD\R19.0\ACAD-B004:409\FixedProfile
HKEY_CURRENT_USER\Software\Autodesk\AutoCAD\R19.0\ACAD-B004:409\Profiles\AutoCAD\General
There might also be others which are directly read through getenv.
Remember that unlike getvar, getenv requires you use the exact same capitalization. E.g. only (getenv "ACAD") will return the support paths, not (getenv "Acad") or (getenv "acad") or any other variant.
Also some new "user defined" sysvars are stored in HKEY_CURRENT_USER\Software\Autodesk\AutoCAD\R19.0\ACAD-B004:409\Variables
HKEY_LOCAL_MACHINE\SOFTWARE\Autodesk\AutoCAD\R19.0\ACAD-B004:409\Variables
HKEY_CURRENT_USER\Software\Autodesk\AutoCAD\R19.0\ACAD-B004:409\Profiles\AutoCAD\Variables
These you get through getvar instead of getenv.